On the Exchange of Carbon Dioxide between the Atmosphere and the Sea
By BERT BOLIN, University of Stockholm (Manuscript received March 3, 1960) Abstract The physical and chemical processes responsible for exchange of carbon dioxide between the atmosphere and the sea are analyzed. It is shown that the rate of transfer is considerably decreased due to the finite rate of hydration of CO2 in water. This is the case both for a smooth water surface where molecular diffusion plays a ro1e in the first few hundredths of a millimeter as well as for a rough sea where turbulence extends all the way to the surface. A general agreement is found between the …