Ocean CO2 Measurements and Calculations
Timothy J. Lueker, Andrew G. Dickson, Charles D. Keeling 15 December 1999 Abstract The partial pressure of carbon dioxide in the ocean’s surface waters, precisely expressed as the fugacity (ƒCO2) is determined from dissolved inorganic carbon (DIC) and total alkalinity (TA) , and the first and second dissociation constants of carbonic acid (K1 and K2) The original measurements of K1 and K2 reported by Mehrbach et al. [Mehrbach, C., Culberson, C.H., Hawley, J.E., Pytkowicz, R.M., 1973. Measurement of the apparent dissociation constants of carbonic acid in seawater at atmospheric pressure. Limnol. Oceanogr. 18, 897–907] are reformulated to give equations for …







